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- W2034386945 abstract "Abstract The microporous crystal of Na 2 [CoB 3 P 2 O 11 (OH)]·0.67H 2 O has been synthesized under hydrothermal conditions and characterized by XRD, FT-IR, DTA-TG techniques and chemical analysis. The molar enthalpies of solution of Na 2 [CoB 3 P 2 O 11 (OH)]·0.67H 2 O (s) in 1 mol·dm –3 HCl (aq), of NaH 2 PO 4 ·2H 2 O (s) in (H 3 BO 3 + HCl + H 2 O) (aq), and of CoCl 2 ·6H 2 O (s) in (NaH 2 PO 4 ·2H 2 O + H 3 BO 3 +HCl + H 2 O) (aq) were measured, respectively. With the incorporation of the previously determined enthalpy of solution of H 3 BO 3 (s) in 1 mol·dm –3 HCl (aq), together with the use of the standard molar enthalpies of formation for CoCl 2 ·6H 2 O (s), NaH 2 PO 4 ·2H 2 O (s), H 3 BO 3 (s), HCl (aq) and H 2 O (l), the standard molar enthalpy of formation of – (5104.7 ± 2.6) kJ·mol –1 for Na 2 [CoB 3 P 2 O 11 (OH)]·0.67H 2 O at T = 298.15 K was obtained on the basis of the appropriate thermochemical cycle. In addition, the molar enthalpy of formation of −4373.9 kJ·mol –1 for [B 3 P 2 O 11 (OH)] 4– has also estimated by a group contribution method, which has been used to predict the Δ f H m o of the others four kinds of Na 2 [M II B 3 P 2 O 11 (OH)]·0.67H 2 O. These estimated data have been further used to compare the stabilities of this series of compounds." @default.
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- W2034386945 date "2012-12-01" @default.
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- W2034386945 title "Standard molar enthalpies of formation for a series of microporous crystals of Na2[MIIB3P2O11(OH)]·0.67H2O (MII=Mg, Mn, Fe, Co, Ni, Cu, Zn)" @default.
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- W2034386945 doi "https://doi.org/10.1016/j.jct.2012.05.034" @default.
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