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• W2034387385 abstract "We report an improved synthesis of 1,1‘-diaminoferrocene, employing the reduction of 1,1‘-diazidoferrocene with H2−Pd/C, along with extensive characterization data for both compounds. Diaminoferrocene undergoes a reversible 1e- oxidation in CH3CN at a potential of −602 mV vs Fc0/+, one of the most negative redox potentials for a ferrocene derivative. The chemical reversibility of this process was confirmed by isolation of the stable, 17-electron [Fc(NH2)2]+ cation as PF6-, OTf-, and TCNE- salts. In the solid state, diaminoferrocene exists in two conformations: one with the NH2 groups eclipsed, and the other with the NH2 groups offset by one-fifth turn around the Cp−Fe−Cp axis. Diazidoferrocene, on the other hand, exhibits only the fully eclipsed conformation in the solid state. The Fe−Cp(centroid) vectors in the diazidoferrocene molecules are roughly aligned with the crystallographic c-axis, and the molecules form layers perpendicular to this axis. The compound is thermally unstable at elevated temperatures, and rapid heating above its melting point results in explosion." @default.
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• W2034387385 date "2000-08-23" @default.
• W2034387385 modified "2023-10-11" @default.
• W2034387385 title "Synthesis, Structure, and Properties of 1,1‘-Diamino- and 1,1‘-Diazidoferrocene" @default.
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• W2034387385 doi "https://doi.org/10.1021/om0004085" @default.
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