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• W2034394067 abstract "Abstract In this paper, we report two easily-synthesized Ir(III) complexes equipped with steric blocking phosphine ligands of bis(2-(diphenylphosphanyl)phenyl) (POP) and triphenylphosphane (PPh 3 ), Ir–POP and Ir–PPh 3 . Their crystal structures, electronic nature, photophysical properties, and phosphorescence self-quenching mechanism are discussed in detail. It is found that the thermally activated intermolecular interaction is responsible for the phosphorescence self-quenching. The introduction of steric blocking ligands into Ir(III) complexes can efficiently suppress the phosphorescence self-quenching in solid state. We successfully realize a solid state emission peaking at 494 nm, with a long excited state lifetime of 15 μs and a high photoluminescence quantum yield of 0.17." @default.
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• W2034394067 date "2011-03-01" @default.
• W2034394067 modified "2023-09-27" @default.
• W2034394067 title "Novel solid state emitting iridium complexes with reduced phosphorescence-self-quenching triggered by steric blocking phosphine ligands" @default.
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• W2034394067 doi "https://doi.org/10.1016/j.ica.2010.12.035" @default.
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