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- W2034395611 abstract "The molecular hyperpolarizabilities, β, of spirolinked push−pull polyenes, where the several 1,4-cyclohexadiene rings linked through the tetrahedral sp3 carbon atoms and electron-donating and -withdrawing groups were introduced in the terminal 1,4-cyclohexadiene rings, were investigated through the ab initio and INDO/S molecular orbital calculations. It is concluded that the spiroconjugation path is applicable to an intervening backbone between the electron-donating and the electron-withdrawing groups, and spirolinked push−pull polyenes have a possibility to be excellent second-order nonlinear optical materials from the standpoint of transparency and relatively large β values." @default.
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- W2034395611 date "1997-01-01" @default.
- W2034395611 modified "2023-10-14" @default.
- W2034395611 title "Theoretical Study of Hyperpolarizabilities of Spirolinked Push−Pull Polyenes" @default.
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- W2034395611 doi "https://doi.org/10.1021/jp9620328" @default.
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