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- W2034395959 abstract "Materials containing metal nanoparticles have been obtained by co-deposition of metal and organic compound vapors onto a surface at 77 K. A new method to encapsulate the metal nanoparticles and mesogenic cyanobiphenyls in a polymer matrix has been developed. Co-condensates of metal vapors (Ag, Mg, Cd, Zn, Pb, Sm, Mn, Sn) with the p-xylylene monomers lead to the polymers at low temperatures. Globular metal particles of 5–8 nm in size encapsulation polymer films have been obtained. The particles size was estimated by means of transmission electron microscopy (TEM). UV-vis, IR and NMR spectroscopy were used to control the processes of nanomaterial preparation. Bimetallic Ag/Pb cryoorganodispersions with particle size of about 5 nm have been obtained. Properties of bimetallic mixed clusters have been computed by ab initio quantum chemistry techniques." @default.
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- W2034395959 date "1999-01-01" @default.
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- W2034395959 title "Cryosynthesis and properties of metal-organic nanomaterials" @default.
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- W2034395959 doi "https://doi.org/10.1016/s0965-9773(99)00309-8" @default.
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