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- W2034404461 abstract "A kinetic-structural model for the curing of epoxy resins with tertiary amines as initiators has been proposed. This model is based on a likely reaction mechanism, which includes the effect of tertiary amine regeneration and the effect of proton donors on the initiation and chain-transfer, and a statistical network build-up methodology based on the independent reactivity of epoxy groups and the random recombination of primary chains. A significant effect of proton donors or impurities is predicted by the model, which can be explained by their likely participation as chain-transfer agents and initiating sites. The occurrence of tertiary amine regeneration has also a profound effect on the curing, but the different regeneration mechanisms have opposite effects and may be counter-balanced. This flexible model is able to explain the curing behavior of different epoxy formulations with tertiary amines as initiator." @default.
- W2034404461 created "2016-06-24" @default.
- W2034404461 creator A5014131033 @default.
- W2034404461 date "2014-06-01" @default.
- W2034404461 modified "2023-10-07" @default.
- W2034404461 title "Theoretical modeling of the effect of proton donors and regeneration reactions in the network build-up of epoxy thermosets using tertiary amines as initiators" @default.
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- W2034404461 doi "https://doi.org/10.1016/j.eurpolymj.2014.03.022" @default.
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