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- W2034407497 abstract "Abstract Gold-catalyzed isomerization of 2-alkynyl-1-tetralones afforded the corresponding 2-naphthylmethyl ketones in good to high yields. For example, the reaction of 2-{4-(methoxyphenyl)methyl}-2-(phenylethynyl)-3,4-dihydronaphthalen-1( 2H )-one and 2-benzyl-2-(phenylethynyl)-3,4-dihydronaphthalen-1( 2H )-one in the presence of 5 mol % of (Ph 3 P)AuCl and 5 mol % of AgOTf in THF at 50 °C gave 2-{1-(4-methoxyphenylmethyl)naphthalen-2-yl}-1-(4-methoxyphenyl)ethanone and 2-(1-benzylnaphthalen-2-yl)-1-phenylethanone in 85% and 96% yields, respectively. The present reaction proceeds through [1,2] alkyl migration followed by oxygen transfer." @default.
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- W2034407497 date "2009-04-07" @default.
- W2034407497 modified "2023-09-26" @default.
- W2034407497 title "ChemInform Abstract: Gold-Catalyzed Consecutive [1,2] Alkyl Migration-Oxygen Transfer Reaction of 2-Alkynyl-1-tetralones." @default.
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- W2034407497 doi "https://doi.org/10.1002/chin.200914096" @default.
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