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- W2034408757 abstract "Several bicyclic compounds bearing a 1,2-cyclopentanediol have been prepared from various anti- or syn-gamma-bromopropargylic diols and cis-dioxolanes under palladium(0) catalysis. The reaction proceeds through a 5-exo-dig cyclocarbopalladation. When the corresponding trans-dioxolanes are used, the only products isolated are obtained from a direct Stille cross-coupling reaction. [reaction: see text]" @default.
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- W2034408757 date "2003-06-01" @default.
- W2034408757 modified "2023-10-06" @default.
- W2034408757 title "Cyclocarbopalladation: 5-Exo-dig Cyclization versus Direct Stille Cross-Coupling Reaction. The Influence of the α,β-Propargylic Substitution" @default.
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- W2034408757 doi "https://doi.org/10.1021/ol034647a" @default.
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