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• W2034408971 abstract "Different pro-oxidant systems are used in degradable low-density polyethylene (LDPE). The main question is the degradation products and not the degradation time from the used materials. The pro-oxidant formulation used consisted of manganese stearate and natural rubber (NR) or manganese stearate and a synthetic, styrene-butadiene copolymer rubber (SBR). The samples were heated in air at 100 degrees C in sealed glass vials. The molecular weight changes were measured by size exclusion chromatography (SEC). The volatile and nonvolatile degradation products have been identified by gas chromatography-mass spectrometry (GC/MS). A wide variety of degradation products were identified, including ketones, carboxylic acids, keto acids, dicarboxylic acids, and furanones as a homologous series. Benzaldehyde, acetophenone, benzoic acid, benzyl benzoate, and two benzene derivative compounds were identified only in the LDPE-SBR system. These aromatic compounds originate from the styrene part of SBR. The advantages using pro-oxidant containing NR are more effective degradation of LDPE without any aromatic degradation products." @default.
• W2034408971 created "2016-06-24" @default.
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• W2034408971 date "2000-09-29" @default.
• W2034408971 modified "2023-10-13" @default.
• W2034408971 title "Great Advantages in Using a Natural Rubber Instead of a Synthetic SBR in a Pro-Oxidant System for Degradable LDPE" @default.
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• W2034408971 doi "https://doi.org/10.1021/bm000050w" @default.
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