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- W2034415350 abstract "The synthesis and mesomorphism of a series of discotic metal complexes of salicylaldimine ligands is reported. None of the ligands was mesomorphic, but the longer chain length complexes showed a Colh phase as evidenced by optical microscopy. Phase diagrams were constructed using rod- and disk-like salicylaldimato complexes, where one was designed to have Lewis acid characteristics and the other Lewis base properties. It was hoped that an associative Lewis acid/base interaction would prevent phase separation of the two components, which may point a way to the realization of a mixture with a biaxial nematic phase. The form of the phase diagrams is discussed." @default.
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- W2034415350 date "2004-11-01" @default.
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- W2034415350 title "Discotic salicylaldimato metal complexes exhibiting columnar mesophases and their mixtures with rod-like salicylaldimato complexes" @default.
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- W2034415350 doi "https://doi.org/10.1080/02678290412331313465" @default.
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