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- W2034421894 abstract "From the angular distribution of the scattered-light intensity for polystyrene in cyclohexane near its critical mixing point, we have measured $frac{{I}_{c,0}}{T}$ (${I}_{c,0}$ being the extrapolated zero-angle scattering intensity), which is directly proportional to the osmotic isothermal compressibility ${ensuremath{chi}}_{T}$, and the long-range correlation length $ensuremath{xi}$. We find ${(frac{{I}_{c,0}}{T})}^{ensuremath{-}1}=B{(frac{T}{{T}_{mathrm{sp}}}ensuremath{-}1)}^{1.24ifmmodepmelsetextpmfi{}0.01}$ and $ensuremath{xi}=(5.83ifmmodepmelsetextpmfi{}0.20){(frac{T}{{T}_{mathrm{sp}}}ensuremath{-}1)}^{ensuremath{-}0.62ifmmodepmelsetextpmfi{}0.02}$ AA{} along the isochore very near the critical concentration, and ${(frac{{I}_{c,0}}{T})}^{ensuremath{-}1}=(2.3ifmmodepmelsetextpmfi{}0.1)B{(1ensuremath{-}frac{T}{{T}_{c}})}^{1.21ifmmodepmelsetextpmfi{}0.02}$ and $ensuremath{xi}=(2.40ifmmodepmelsetextpmfi{}0.12){(1ensuremath{-}frac{T}{{T}_{c}})}^{0.65ifmmodepmelsetextpmfi{}0.03}$ AA{} along the concentrated phase and ${(frac{{I}_{c,0}}{T})}^{ensuremath{-}1}=(5.9ifmmodepmelsetextpmfi{}0.3)B{(1ensuremath{-}frac{T}{{T}_{c}})}^{1.25ifmmodepmelsetextpmfi{}0.03}$ along the dilute phase of the coexistence curve. In addition, we have determined the value of the critical exponent ($ensuremath{delta}ensuremath{simeq}4.4$) which describes the concentration dependence of the chemical potential $ensuremath{mu}$ along the critical isotherm." @default.
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- W2034421894 date "1975-12-01" @default.
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- W2034421894 title "Osmotic compressibility and correlation range of a macromolecular solution near its critical mixing point" @default.
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- W2034421894 doi "https://doi.org/10.1103/physreva.12.2606" @default.
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