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- W2034452478 abstract "A fascinating mechanistic study of ynamido−palladium−π-allyl complexes is described that features isolation of a unique silyl ketenimine via aza-Claisen rearrangement, which can be accompanied by an unusual thermal N-to-C 1,3-Ts shift in the formation of tertiary nitriles and a novel cyclopentenimine formation via a palladium-catalyzed aza-Rautenstrauch-type cyclization pathway." @default.
- W2034452478 created "2016-06-24" @default.
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- W2034452478 date "2010-03-25" @default.
- W2034452478 modified "2023-09-23" @default.
- W2034452478 title "A Divergent Mechanistic Course of Pd(0)-Catalyzed Aza-Claisen Rearrangement and Aza-Rautenstrauch-Type Cyclization of <i>N</i>-Allyl Ynamides" @default.
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- W2034452478 doi "https://doi.org/10.1021/ol100446p" @default.
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