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- W2034453035 abstract "Die Autoxidation von bicyclischen Iminen 4a–d und 18a, b führt über eine Fragmentierung der als instabile Zwischenprodukte entstehenden α-Iminohydroperoxide zu Δ9-Dehydro-4-chinolizidon-Derivaten 6 bzw. 20. Die Bildung weiterer Produkte der Autoxidation wird diskutiert. In einigen Fällen stellt diese Umlagerung eine präparativ geeignete Darstellung von Chinolizidin-Derivaten dar, da die Synthese der Ausgangs-Imine einfach ist. Autoxidation of Cyclic Imines, II. Synthesis of Quinolizidine Derivatives Autoxidation of bicyclic imines 4a–d and 18a, b yields Δ9-dehydro-4-quinolizidone derivatives 6 and 20, respectively. Mostly, the quinolizidine compounds are formed via labile α-iminohydroperoxides by fragmentation and rearrangement. For some cases the described reaction is a preparative useful route to quinolizidine derivatives, since the starting imines are easily available." @default.
- W2034453035 created "2016-06-24" @default.
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- W2034453035 date "1982-04-01" @default.
- W2034453035 modified "2023-10-08" @default.
- W2034453035 title "Zur Autoxidation von cyclischen Iminen, II. Synthese von Chinolizidin‐Derivaten" @default.
- W2034453035 cites W2007613261 @default.
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- W2034453035 doi "https://doi.org/10.1002/cber.19821150437" @default.
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