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- W2034453365 endingPage "1619" @default.
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- W2034453365 abstract "A computational investigation on the origin of the stereoselectivity of 6-exo-trig radical cyclization of α,β-unsaturated ester-tethered sugars has revealed that a boat-like transition state, which keeps the ester in a planar conformation, holds the chiral information. Following this model, the stereocenter to which the ester functionality is connected reports the chirality to the newly formed stereocenter via a 1,4-transfer mechanism." @default.
- W2034453365 created "2016-06-24" @default.
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- W2034453365 date "2010-01-01" @default.
- W2034453365 modified "2023-09-24" @default.
- W2034453365 title "Unravelling the stereoselectivity in 6-exo-trig radical cyclization of α,β-unsaturated ester-tethered sugars. A tale of two stereocenters" @default.
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- W2034453365 doi "https://doi.org/10.1039/b923414d" @default.
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