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- W2034454944 abstract "Abstract We analyzed the nucleation of rutile and anatase from titanium dioxide (TiO2) melt by a thermodynamic calculation using estimated values of the interfacial energy between the condensed phases and the liquid phase in the pure TiO2 system. The results show that the as-solidified phase depends on the solidification temperature or degree of supercooling of the TiO2 melt. Under a high cooling rate, anatase nucleates directly from the melt below 2057 K, while stable rutile solidifies at a temperature close to the melting point of TiO2. This result agrees with the experimental observation that anatase is formed in a rapid cooling process, while rutile is formed under near-equilibrium solidification conditions." @default.
- W2034454944 created "2016-06-24" @default.
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- W2034454944 date "2002-07-01" @default.
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- W2034454944 title "Thermodynamic analysis of nucleation of anatase and rutile from TiO2 melt" @default.
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- W2034454944 doi "https://doi.org/10.1016/s0022-0248(02)01438-0" @default.
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