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• W2034456073 abstract "Poly[(μ4-pyrazine-2,5-dicarboxyl­ato)cadmium(II)], [Cd(C6H2N2O4)]n or [Cd(pzdc)]n (pzdc is the pyrazine-2,5-dicarboxyl­ate dianion), has been synthesized hydro­thermally. The asymmetric unit consists of a CdII atom and two independent halves of pzdc ligands that can be expanded via inversion through the centres of the ligands so that each ligand binds to four CdII atoms with the same binding mode using six donor atoms. The CdII centre is in a distorted octa­hedral coordination geometry with four O- and two N-atom donors from four pzdc ligands. The infinite linkage of the metal atoms and ligands forms a three-dimensional framework with a recta­ngular channel which is so narrow that there is no measurable void space in the overall structure. This coordination polymer represents the first example of (4,4,4)-connected three-nodal framework." @default.
• W2034456073 created "2016-06-24" @default.
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• W2034456073 date "2008-12-06" @default.
• W2034456073 modified "2023-10-16" @default.
• W2034456073 title "A three-dimensional pyrazine-2,5-dicarboxylate Cd^IIcoordination framework with new (4,4,4)-connected three-nodal topology" @default.
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• W2034456073 doi "https://doi.org/10.1107/s0108270108040080" @default.
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