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- W2034456380 abstract "Abstract Two samples of MFI-type ferrisilicate molecular sieves that were synthesized in the presence of fluoride ions, and having a Si/Fe molar ratio of 31 and 56, were characterized by optical and X-ray (at the iron K-edge) absorption spectroscopies. In the as-synthesized samples, the Fe3+ ions are present in the zeolite framework in a four-fold coordination with an average FeO distance ∼ 1.86–1.87 A. After template removal by calcination and subsequent hydration, most of the iron atoms are in a distorted tetrahedral environment with a second-neighbor oxygen subshell at an FeO distance of 2.18 A. This second subshell might be assigned to water sorbate molecules in interaction with Fe3+ Lewis acid sites in the framework." @default.
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- W2034456380 date "1992-01-01" @default.
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- W2034456380 title "Optical and X-ray absorption spectroscopy studies of iron MFI-type zeolite prepared in fluoride medium" @default.
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- W2034456380 doi "https://doi.org/10.1016/0144-2449(92)90013-f" @default.
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