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• W2034457567 endingPage "5269" @default.
• W2034457567 startingPage "5261" @default.
• W2034457567 abstract "An elastomer was prepared from biodegradable components as a potential biomaterial for drug delivery and tissue engineering applications. The elastomer was synthesized in two steps. First, a star copolymer (SCP) was manufactured via ring opening polymerization of ε-caprolactone (ε-CL) with d,l-lactide using glycerol as initiator and stannous 2-ethylhexanoate as catalyst. This living SCP was further reacted with different ratios of a crosslinking monomer, 2,2-bis(ε-CL-4-yl)-propane in the presence of ε-CL as a solvent and co-monomer. The elastomers had very low glass transitions (−32°C), sol contents ranging from 17% to 37%, and were soft and weak with physical properties similar to those of natural elastomers such as elastin. The physical properties decreased in a logarithmic fashion with time when degraded in phosphate buffered saline, indicative of first-order degradation kinetics. The elastomers degraded relatively slowly, with degradation being incomplete after 12 weeks." @default.
• W2034457567 created "2016-06-24" @default.
• W2034457567 creator A5036146706 @default.
• W2034457567 creator A5045753444 @default.
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• W2034457567 date "2004-10-01" @default.
• W2034457567 modified "2023-10-17" @default.
• W2034457567 title "Synthesis, characterization and in vitro degradation of a biodegradable elastomer" @default.
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• W2034457567 doi "https://doi.org/10.1016/j.biomaterials.2003.12.024" @default.
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