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- W2034457944 abstract "The synthesis and X-ray crystal structure of tetrakis[1-(o-carboxymethoxyphenoxy)-2-(o-hydroxyphenoxy)-ethanato(1–)]dipotassiumcobalt(II), [Co(L2K)2], a novel neutral K–Co–K complex, is reported. The cobalt(II) ion is tetrahedrally co-ordinated by four carboxyl oxygens, one from each of four open-chain polyether hydroxy-acid anion ligands L–. The polyether ligands are held in the correct positions to co-ordinate two potassium ions, each potassium being co-ordinated by ten oxygen atoms. Four interligand hydrogen bonds from hydroxy groups to carboxy oxygens add further stability to the [Co(L2K)2] structure. Crystals are monoclinic, a= 17.052(4), b= 14.263(4), c= 26.226(6)A, β= 106.71(2)°, and Z= 4. R= 0.069 for 2 338 reflections." @default.
- W2034457944 created "2016-06-24" @default.
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- W2034457944 date "1982-01-01" @default.
- W2034457944 modified "2023-10-14" @default.
- W2034457944 title "Co-ordination of alkali metals by open-chain polyethers in transition-metal complexes. Part 1. X-Ray crystal and molecular structure of tetrakis[1-o-carboxymethoxyphenoxy)-2-(o-hydroxyphenoxy)ethanato(1–)]dipotassiumcobalt(II), a trinuclear potassium–cobalt–potassium complex" @default.
- W2034457944 doi "https://doi.org/10.1039/dt9820001239" @default.
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