FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034458968> ?p ?o ?g. }

• W2034458968 endingPage "2394" @default.
• W2034458968 startingPage "2387" @default.
• W2034458968 abstract "The reactions of 4,7-phenanthroline (4,7-phen) with a variety of metal salts have been investigated and the products structurally characterised by single crystal X-ray diffraction. Reaction of CoX2 (X = Cl, Br) or M(NO3)2 (M = Cd, Zn, Ni) salts with 4,7-phen all afford one-dimensional coordination polymers, [CoX2(4,7-phen)]∞ (1, 2) or [M(NO3)2(4,7-phen)(H2O)]∞ (M = Cd 3, Zn 4, Ni 5), in which the metal centres are linked via 4,7-phen ligands which act in a bridging bidentate manner. The remaining metal coordination sites are occupied by either halide (1, 2) or NO3− and H2O ligands (3–5). In{[Ni(NO3)2(4,7-phen)(H2O)]·(4,7-phen)}∞, 5 an additional, uncoordinated, molecule of 4,7-phen is included in the structure, hydrogen bonded to a coordinated H2O molecule. In contrast, reaction of CuX2 (X = Cl, Br) or Cu(NO3)2 with 4,7-phen leads to the formation of discrete complexes, [CuX2(4,7-phen)2] (X = Cl 6, Br 7, NO38) in which the N-donor ligand coordinates in a monodentate fashion and π–π interactions between coordinated 4,7-phen molecules generate an extended structure in the solid state. Investigation of the phase purity of 4 and 5 revealed that in the case of 4 the coordination polymer formed only in the presence of a previously reported hydrogen bonded structure, while 5 was shown to be contaminated with an unidentified phase. The rôle and diversity of the interactions adopted by 4,7-phen in forming coordination polymers and related species are discussed." @default.
• W2034458968 created "2016-06-24" @default.
• W2034458968 creator A5015224570 @default.
• W2034458968 creator A5058602636 @default.
• W2034458968 creator A5060460715 @default.
• W2034458968 creator A5073383060 @default.
• W2034458968 date "2003-01-01" @default.
• W2034458968 modified "2023-09-27" @default.
• W2034458968 title "The rôle of 4,7-phenanthroline in coordination polymer construction" @default.
• W2034458968 cites W1957108303 @default.
• W2034458968 cites W1966555774 @default.
• W2034458968 cites W1970622048 @default.
• W2034458968 cites W1972646318 @default.
• W2034458968 cites W1972772118 @default.
• W2034458968 cites W1974045595 @default.
• W2034458968 cites W1975592620 @default.
• W2034458968 cites W1978659336 @default.
• W2034458968 cites W1989941486 @default.
• W2034458968 cites W1996093891 @default.
• W2034458968 cites W2006377435 @default.
• W2034458968 cites W2007068681 @default.
• W2034458968 cites W2013564410 @default.
• W2034458968 cites W2014189802 @default.
• W2034458968 cites W2015216092 @default.
• W2034458968 cites W2017593837 @default.
• W2034458968 cites W2018342923 @default.
• W2034458968 cites W2022527088 @default.
• W2034458968 cites W2028997946 @default.
• W2034458968 cites W2032885218 @default.
• W2034458968 cites W2036170029 @default.
• W2034458968 cites W2039111982 @default.
• W2034458968 cites W2050065836 @default.
• W2034458968 cites W2050915803 @default.
• W2034458968 cites W2081503801 @default.
• W2034458968 cites W2082561386 @default.
• W2034458968 cites W2084024682 @default.
• W2034458968 cites W2097560958 @default.
• W2034458968 cites W2112724673 @default.
• W2034458968 cites W2112867858 @default.
• W2034458968 cites W2142594455 @default.
• W2034458968 cites W2143609582 @default.
• W2034458968 cites W2146236667 @default.
• W2034458968 cites W2164043498 @default.
• W2034458968 doi "https://doi.org/10.1039/b302807k" @default.
• W2034458968 hasPublicationYear "2003" @default.
• W2034458968 type Work @default.
• W2034458968 sameAs 2034458968 @default.
• W2034458968 citedByCount "11" @default.
• W2034458968 countsByYear W20344589682016 @default.
• W2034458968 countsByYear W20344589682019 @default.
• W2034458968 countsByYear W20344589682020 @default.
• W2034458968 crossrefType "journal-article" @default.
• W2034458968 hasAuthorship W2034458968A5015224570 @default.
• W2034458968 hasAuthorship W2034458968A5058602636 @default.
• W2034458968 hasAuthorship W2034458968A5060460715 @default.
• W2034458968 hasAuthorship W2034458968A5073383060 @default.
• W2034458968 hasConcept C112887158 @default.
• W2034458968 hasConcept C115624301 @default.
• W2034458968 hasConcept C116569031 @default.
• W2034458968 hasConcept C170493617 @default.
• W2034458968 hasConcept C171560689 @default.
• W2034458968 hasConcept C178516000 @default.
• W2034458968 hasConcept C178790620 @default.
• W2034458968 hasConcept C179104552 @default.
• W2034458968 hasConcept C185592680 @default.
• W2034458968 hasConcept C2777660389 @default.
• W2034458968 hasConcept C2781432337 @default.
• W2034458968 hasConcept C32909587 @default.
• W2034458968 hasConcept C544153396 @default.
• W2034458968 hasConcept C55352516 @default.
• W2034458968 hasConcept C55493867 @default.
• W2034458968 hasConcept C68913812 @default.
• W2034458968 hasConcept C71240020 @default.
• W2034458968 hasConcept C8010536 @default.
• W2034458968 hasConceptScore W2034458968C112887158 @default.
• W2034458968 hasConceptScore W2034458968C115624301 @default.
• W2034458968 hasConceptScore W2034458968C116569031 @default.
• W2034458968 hasConceptScore W2034458968C170493617 @default.
• W2034458968 hasConceptScore W2034458968C171560689 @default.
• W2034458968 hasConceptScore W2034458968C178516000 @default.
• W2034458968 hasConceptScore W2034458968C178790620 @default.
• W2034458968 hasConceptScore W2034458968C179104552 @default.
• W2034458968 hasConceptScore W2034458968C185592680 @default.
• W2034458968 hasConceptScore W2034458968C2777660389 @default.
• W2034458968 hasConceptScore W2034458968C2781432337 @default.
• W2034458968 hasConceptScore W2034458968C32909587 @default.
• W2034458968 hasConceptScore W2034458968C544153396 @default.
• W2034458968 hasConceptScore W2034458968C55352516 @default.
• W2034458968 hasConceptScore W2034458968C55493867 @default.
• W2034458968 hasConceptScore W2034458968C68913812 @default.
• W2034458968 hasConceptScore W2034458968C71240020 @default.
• W2034458968 hasConceptScore W2034458968C8010536 @default.
• W2034458968 hasIssue "12" @default.
• W2034458968 hasLocation W20344589681 @default.
• W2034458968 hasOpenAccess W2034458968 @default.
• W2034458968 hasPrimaryLocation W20344589681 @default.
• W2034458968 hasRelatedWork W1164717787 @default.
• W2034458968 hasRelatedWork W1970406290 @default.

• next