Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034490460> ?p ?o ?g. }
- W2034490460 endingPage "799" @default.
- W2034490460 startingPage "789" @default.
- W2034490460 abstract "Two new porphyrins, meso-tris-3,4-dimethoxyphenyl-mono-(4-pyridyl)porphyrin (H2MPy3,4DMPP) and meso-tris-3-methoxy-4-hydroxyphenyl-mono-(4-pyridyl)porphyrin (H2MPy3M4HPP), and their ruthenium analogs obtained by coordination of [Ru(bpy)2Cl]+ groups (where bpy = 2,2′-bipyridine) to the pyridyl nitrogens have been synthesized and studied by electronic absorption spectroscopy, cyclic voltammetry and spectroelectrochemistry. These ruthenated porphyrins couple Ru chromophores to porphyrins containing electroactive meso-substituents. The highest energy electronic absorption for the ruthenated complexes is assigned as a bpy(π) → bpy(π*) intraligand charge transfer while the next lowest energy electronic absorption is assigned as Ru(dπ) → bpy(π*) metal-to-ligand charge transfer (MLCT) transition. The RuIII/II couples occur at approximately 0.95 V versus the SHE reference electrode in acetonitrile solutions. The first oxidation of the porphyrin is localized on the 3,4-dimethoxyphenyl and 3-methoxy-4-hydroxyphenyl substituents, respectively. Electroactive surfaces result from adsorption of these compounds onto glassy carbon electrodes followed by anodic cycling in acidic media." @default.
- W2034490460 created "2016-06-24" @default.
- W2034490460 creator A5010921119 @default.
- W2034490460 creator A5046876518 @default.
- W2034490460 creator A5062534048 @default.
- W2034490460 creator A5063970954 @default.
- W2034490460 date "2006-02-01" @default.
- W2034490460 modified "2023-09-25" @default.
- W2034490460 title "Synthesis, characterization and electrode adsorption studies of porphyrins coordinated to ruthenium(II) polypyridyl complexes" @default.
- W2034490460 cites W1964248782 @default.
- W2034490460 cites W1971442879 @default.
- W2034490460 cites W1974689604 @default.
- W2034490460 cites W1977172811 @default.
- W2034490460 cites W1977935357 @default.
- W2034490460 cites W1980065572 @default.
- W2034490460 cites W1981500672 @default.
- W2034490460 cites W1987663334 @default.
- W2034490460 cites W1988708418 @default.
- W2034490460 cites W1989526692 @default.
- W2034490460 cites W1996492235 @default.
- W2034490460 cites W2000576151 @default.
- W2034490460 cites W2008234571 @default.
- W2034490460 cites W2011548254 @default.
- W2034490460 cites W2012657929 @default.
- W2034490460 cites W2018351370 @default.
- W2034490460 cites W2024840766 @default.
- W2034490460 cites W2045906906 @default.
- W2034490460 cites W2048067383 @default.
- W2034490460 cites W2048758248 @default.
- W2034490460 cites W2053042614 @default.
- W2034490460 cites W2061865779 @default.
- W2034490460 cites W2064525366 @default.
- W2034490460 cites W2069534755 @default.
- W2034490460 cites W2070966771 @default.
- W2034490460 cites W2071756355 @default.
- W2034490460 cites W2071832665 @default.
- W2034490460 cites W2073970300 @default.
- W2034490460 cites W2075929994 @default.
- W2034490460 cites W2078043636 @default.
- W2034490460 cites W2080022626 @default.
- W2034490460 cites W2092820083 @default.
- W2034490460 cites W2095637504 @default.
- W2034490460 cites W2112611828 @default.
- W2034490460 cites W2153960616 @default.
- W2034490460 cites W2321905411 @default.
- W2034490460 cites W2952961934 @default.
- W2034490460 cites W6558688 @default.
- W2034490460 cites W2014073918 @default.
- W2034490460 doi "https://doi.org/10.1016/j.ica.2005.04.037" @default.
- W2034490460 hasPublicationYear "2006" @default.
- W2034490460 type Work @default.
- W2034490460 sameAs 2034490460 @default.
- W2034490460 citedByCount "17" @default.
- W2034490460 countsByYear W20344904602013 @default.
- W2034490460 countsByYear W20344904602014 @default.
- W2034490460 countsByYear W20344904602016 @default.
- W2034490460 countsByYear W20344904602020 @default.
- W2034490460 crossrefType "journal-article" @default.
- W2034490460 hasAuthorship W2034490460A5010921119 @default.
- W2034490460 hasAuthorship W2034490460A5046876518 @default.
- W2034490460 hasAuthorship W2034490460A5062534048 @default.
- W2034490460 hasAuthorship W2034490460A5063970954 @default.
- W2034490460 hasConcept C115624301 @default.
- W2034490460 hasConcept C119824511 @default.
- W2034490460 hasConcept C121332964 @default.
- W2034490460 hasConcept C125287762 @default.
- W2034490460 hasConcept C147789679 @default.
- W2034490460 hasConcept C161790260 @default.
- W2034490460 hasConcept C17525397 @default.
- W2034490460 hasConcept C178790620 @default.
- W2034490460 hasConcept C179104552 @default.
- W2034490460 hasConcept C185592680 @default.
- W2034490460 hasConcept C192468462 @default.
- W2034490460 hasConcept C24890656 @default.
- W2034490460 hasConcept C2776422427 @default.
- W2034490460 hasConcept C2777463227 @default.
- W2034490460 hasConcept C2777869211 @default.
- W2034490460 hasConcept C2779336533 @default.
- W2034490460 hasConcept C2779480358 @default.
- W2034490460 hasConcept C52859227 @default.
- W2034490460 hasConcept C555196967 @default.
- W2034490460 hasConcept C62520636 @default.
- W2034490460 hasConcept C75473681 @default.
- W2034490460 hasConcept C8010536 @default.
- W2034490460 hasConceptScore W2034490460C115624301 @default.
- W2034490460 hasConceptScore W2034490460C119824511 @default.
- W2034490460 hasConceptScore W2034490460C121332964 @default.
- W2034490460 hasConceptScore W2034490460C125287762 @default.
- W2034490460 hasConceptScore W2034490460C147789679 @default.
- W2034490460 hasConceptScore W2034490460C161790260 @default.
- W2034490460 hasConceptScore W2034490460C17525397 @default.
- W2034490460 hasConceptScore W2034490460C178790620 @default.
- W2034490460 hasConceptScore W2034490460C179104552 @default.
- W2034490460 hasConceptScore W2034490460C185592680 @default.
- W2034490460 hasConceptScore W2034490460C192468462 @default.
- W2034490460 hasConceptScore W2034490460C24890656 @default.
- W2034490460 hasConceptScore W2034490460C2776422427 @default.
- W2034490460 hasConceptScore W2034490460C2777463227 @default.