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• W2034502045 abstract "The electronic spectra of 1,3-cyclohexadiene, (Z)- and (E)-1,3,5-hexatriene were measured and interpreted. The absorptions between 220 and 280 nm in the gas phase are π → πx-transitions whereas the second absorption (180-210 nm) in these compounds is considered to be a Rydberg transition. A weak π → πx-transition is hidden by the latter absorption in (Z)-hexatriene. The band in the solution spectrum of cyclohexadiene at 190 nm is thought to correspond to the band at 175 nm in gaseous cyclohexadiene. Triplet absorption spectra were measured in heavy atom solvents (CH2I2, CHBr3). A scheme of energy levels is given." @default.
• W2034502045 created "2016-06-24" @default.
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• W2034502045 date "1973-01-01" @default.
• W2034502045 modified "2023-10-18" @default.
• W2034502045 title "Some aspects of the electronic spectra of 1,3-cyclohexadiene, <i>(E)</i> - and <i>(Z)</i> -1,3,5-hexatriene" @default.
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• W2034502045 doi "https://doi.org/10.1002/recl.19730921102" @default.
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