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- W2034535523 abstract "α′-NaV 2 O 5 transforms at T C = 34 K, and the origin of the phase transition seems to be caused by the charge order and spin-Peierls mechanism. However the experiments which reveal the existence of charge order are very little. We measured XANES of V atoms which relates to the valence of V. It was found that the valences of V atoms in NaV 2 O 5 were V 4.5+ in the high temperature phase by comparing pre-edge and XANES of NaV 2 O 5 with that of LiV$_ 2 O 5 , CaV 2 O 5 and V 2 O 5 . The analysis of EXAFS also shows the environment of the V 4.5+ state." @default.
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- W2034535523 date "2001-03-01" @default.
- W2034535523 modified "2023-09-25" @default.
- W2034535523 title "XANES study of charge ordering on the spin-Peierls phase transition of α′-NaV<sub>2</sub>O<sub>5</sub>" @default.
- W2034535523 doi "https://doi.org/10.1107/s0909049500020872" @default.
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