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- W2034556247 abstract "The enantioselective synthesis of (8R,8aS)-hcxahydro-8-methyl-5(1H)-indolizinone ((−)-13), which is a synthetic intermediate of 5,8-disubstituted indolizidine alkaloids has been carried out. Reaction of ethyl (E)-(4R, 5R)-8-benzyloxy-4, 5-epoxy-4-methyl-2-octenoate (4) with formic acid in the presence of Pd2(dba)3CHCl3 and n-Bu3P as a catalyst gave ethyl (E)-(4R, 5R)-8-benzyloxy-5-hydroxy-4-methyl-2-octenoate (5), which was converted to (−)-13 in 8 and steps." @default.
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- W2034556247 date "1993-07-01" @default.
- W2034556247 modified "2023-09-23" @default.
- W2034556247 title "A chiral synthesis of (8R,8aS)-hexahydro-8-methyl-5(1H)-indolizinone" @default.
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- W2034556247 doi "https://doi.org/10.1016/s0957-4166(00)80326-2" @default.
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