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- W2034603334 abstract "In this study, physical and thermodynamic properties of poly(2-phenyl-1,3-dioxolane-4-yl-methyl-methacrylate-co-styrene) (PDMMA-ST) were investigated by using inverse gas chromatography. Two groups of solvents with different chemical natures and polarities were used to obtain information about PDMMA-ST-solvent interactions: alcohols and alkanes. The specific retention volume (Vg 0), the sorption enthalpy (ΔH1 S), sorption free energy (ΔG1 S), sorption entropy (ΔS1 S), the weight fraction activity coefficients of solute probes at infinite dilution (Ω 1 ∞), and Flory-Huggins interaction parameters (χ 12 ∞) between polymer and solvents were determined for the interactions of PDMMA-ST with alcohols and alkanes by inverse gas chromatography in the temperature range of 333–473 K. Also, the solubility parameters of PDMMA-ST at infinite dilution were found by plotting the graph of [(δ 1 2/RT) - χ 12 ∞/V1] versus solubility parameters, δ 1, of probes." @default.
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- W2034603334 date "2006-06-01" @default.
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- W2034603334 title "Analysis of Physical and Thermodynamic Properties of Poly(2-Phenyl-1,3-Dioxolane-4-Yl-Methyl-Methacrylate-Co-Styrene) Polymer with Inverse Gas Chromatography" @default.
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- W2034603334 doi "https://doi.org/10.1080/03602550600611859" @default.
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