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- W203460382 abstract "Summary * It has been shown that according to the influence upon the electronic spectra a solvent may be looked upon as an external dielectric medium only in regard to complex and some simple polyatomic molecules. I t has been established that such a treatment of a solvent remains possible even at a considerable drop of its concentration, which accompanies the transition of liquid solutions into a gaseous state. The values of the integrals of absorption and also the lifetimes of excited molecules of phthalimide and some of its derivatives have been investigated experimentally in vapor state and in the solution of several solvents. Different models of the system, dissolved molecule-solvent, were examined and the necessity of considering the internal field of a solution has been proved. I t has been established that agreement of the experimental data with the well-known relations is achieved by introducing the corrections according to Onsager or Lorentz. Besides, investigations dealing with the influence of internal field upon the position of the electronic spectra and the intensity of Raman spectra have been looked into." @default.
- W203460382 created "2016-06-24" @default.
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- W203460382 date "1962-01-01" @default.
- W203460382 modified "2023-09-23" @default.
- W203460382 title "THE INFLUENCE OF A SOLVENT UPON THE ELECTRONIC SPECTRA OF POLYATOMIC MOLECULES" @default.
- W203460382 doi "https://doi.org/10.1016/b978-1-4832-1331-6.50004-3" @default.
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