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- W2034606469 abstract "A simple molecular theory is developed in order to discuss the thermodynamic stability of chain-folded crystals. The partition function for a crystal containing different fold loops is formulated for a monodisperse polymer in terms of the lattice model; the analytical evaluation is made by using the maximum term method. The free energy calculated decreases linearly with decreasing the number of fold loops, i.e., its minimum corresponds to the extended-chain-type crystal. However, a lamellar-type crystal with long fold period and tight fold loops is also actually stable owing to the existence of high activation free energy barriers between them. The average number of monomer units comprised in the loop is estimated to be 5–7 irrespective of the lamellar thickness. The irreversible lamellar thickening and melting behavior of folded-chain crystals can be explained from this model. The results are also valid for the polydisperse system having a chain length distribution; it gives the crystal of nonuniform but well-defined lamellar thickness." @default.
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- W2034606469 date "1978-02-15" @default.
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- W2034606469 title "Statistical thermodynamics of chain‐folded polymer crystals" @default.
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- W2034606469 doi "https://doi.org/10.1063/1.435897" @default.
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