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- W2034608267 abstract "Magnetic circularly polarized luminescence (MCPL) and time-resolved luminescence of Ru(bpy)2+3 taken through the glass-fluid transition can be interpreted by considering two processes occurring at somewhat different rates. One, a rapid solvent dipole relaxation red-shift of the luminescence, the other a localization of the transferred electron on one ligand. The localization is evidenced by a marked drop in the MCPL signal, a change in the luminescence Franck-Condon distribution and a change in the vibrational spacing. Time-evolution data taken at different energies, near the transition temperature, show markedly different and non-exponential behaviour corresponding to the rapid decay of a delocalized species to a localized species emitting at lower energies." @default.
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- W2034608267 date "1986-07-01" @default.
- W2034608267 modified "2023-09-26" @default.
- W2034608267 title "Time-resolved luminescence and MCPL of Ru(bpy)2+3 in glassy solvents at the fluid-glass transition" @default.
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- W2034608267 doi "https://doi.org/10.1016/0009-2614(86)80606-6" @default.
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