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• W2034608339 abstract "C2-symmetric chiral bisformamides have been shown to catalyze the asymmetric one-pot, three-component Strecker reaction, which produced the α-amino nitriles in excellent yields (up to 99%) with good enantioselectivities (up to 86% ee). Optically pure products could be obtained after a single recrystallization. A possible transition state (TS 1) has been proposed to explain the origin of asymmetric inductivity and reactivity according to the geometry of catalyst 2a optimized at the B3LYP/6-31G(d) level and the absolute configuration of product 4a." @default.
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• W2034608339 date "2007-08-30" @default.
• W2034608339 modified "2023-10-02" @default.
• W2034608339 title "Chiral Bisformamides as Effective Organocatalysts for the Asymmetric One-Pot, Three-Component Strecker Reaction" @default.
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• W2034608339 doi "https://doi.org/10.1021/jo701307f" @default.
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