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• W2034609632 abstract "Thermal and photochemical reactions of La2@C78 with 2-admantane-2,3-[3H]-diazirine are investigated. Four isomers of the monoadduct (La2@C78Ad) synthesized by the photoreaction are isolated by HPLC and characterized by mass, UV-vis-NIR absorption, cyclic voltammogram and differential pulse voltammogram spectroscopy, proton and 13C NMR spectroscopic analysis, single-crystal X-ray diffraction analysis, and theoretical approaches. The addition reactions occur at both the [5,6] and [6,6] positions. X-ray and theoretical studies indicate that one of the monoadduct isomers has an open structure with two La atoms on the C3 axis of the D3h cage of La2@C78." @default.
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• W2034609632 date "2007-12-29" @default.
• W2034609632 modified "2023-10-16" @default.
• W2034609632 title "Addition of Adamantylidene to La₂@C₇₈: Isolation and Single-Crystal X-ray Structural Determination of the Monoadducts" @default.
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• W2034609632 doi "https://doi.org/10.1021/ja076462v" @default.
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