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- W2034621574 abstract "Organic microdots of fluorescent bis(N,N-di-p-tolylamino-p-styryl)benzene molecules were self-organized by vapor deposition onto the KCl (001) surface kept at 180 °C. In situ optical microscopy revealed that the microdots preferably nucleated themselves along the KCl [100] step so that they were aligned partly in a linear manner. As the deposition was continued, the number of nuclei reached the saturation point and their diameters increased from a few submicrometers to several micrometers. Finally, the adjacent microdots coalesced resulting in a diameter larger than 10 μm. Such microdot growth was attributed to molecular migration on the substrate surface with a long diffusion length based on the molecular bearing effect of the peripheral bulky group. The as-deposited microdots exhibited a bluish-green fluorescence, which was considerably quenched under UV excitation in air due to photooxidation of the π-conjugating backbone. When the microdots were covered with a MgF2 layer, this fluorescence quenching was thoroughly prevented." @default.
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- W2034621574 date "2001-08-11" @default.
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- W2034621574 title "Self-Organized Organic Microdots of Fluorescent Diaminodistyrylbenzene Molecules" @default.
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- W2034621574 doi "https://doi.org/10.1021/la010474r" @default.
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