Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034633070> ?p ?o ?g. }
Showing items 1 to 85 of
85
with 100 items per page.
- W2034633070 endingPage "333" @default.
- W2034633070 startingPage "326" @default.
- W2034633070 abstract "The kinetics of the oxidation of toluene catalyzed by cobaltic acetate in acetic acid have been studied at 60 °C. The oxidation proceeds without induction period, and the maximum absoiption rate of oxygen as well as the maximum reduction rate of cobaltic ion were observed at the beginning of the reaction. Eoth maximum rates can be expressed as follows, −dO2dt = k[φ-CH3][Co(III)]2[Co(II)]−1−dCo(III)dt = k′[φ-CH3][Co(III)]2[Co(II)]−1 with k′k ~ 1.7. The oxidation product was exclusively benzaldehyde at the early stage of oxidation. The following mechanisms are proposed: (1) The oxidation of toluene to benzyl radical proceeds by the reaction of toluene with a dimer of cobaltic ion; (2) Benzylperoxy radical is oxidized to benzaldehyde by a cobaltic ion." @default.
- W2034633070 created "2016-06-24" @default.
- W2034633070 creator A5052577601 @default.
- W2034633070 creator A5078371702 @default.
- W2034633070 date "1972-06-01" @default.
- W2034633070 modified "2023-10-16" @default.
- W2034633070 title "The autoxidation of aromatic hydrocarbons catalyzed with cobaltic acetate in acetic acid solution I. The oxidation of toluene" @default.
- W2034633070 cites W1970008898 @default.
- W2034633070 cites W2003133287 @default.
- W2034633070 cites W2032181024 @default.
- W2034633070 cites W2037685314 @default.
- W2034633070 cites W2050940314 @default.
- W2034633070 cites W2052689821 @default.
- W2034633070 cites W2073643486 @default.
- W2034633070 cites W2074714385 @default.
- W2034633070 cites W2076319794 @default.
- W2034633070 cites W2085705518 @default.
- W2034633070 cites W2315638917 @default.
- W2034633070 cites W2321503878 @default.
- W2034633070 cites W2321836976 @default.
- W2034633070 cites W2324880744 @default.
- W2034633070 cites W2327023924 @default.
- W2034633070 doi "https://doi.org/10.1016/0021-9517(72)90234-5" @default.
- W2034633070 hasPublicationYear "1972" @default.
- W2034633070 type Work @default.
- W2034633070 sameAs 2034633070 @default.
- W2034633070 citedByCount "43" @default.
- W2034633070 countsByYear W20346330702013 @default.
- W2034633070 countsByYear W20346330702015 @default.
- W2034633070 countsByYear W20346330702016 @default.
- W2034633070 countsByYear W20346330702017 @default.
- W2034633070 countsByYear W20346330702019 @default.
- W2034633070 countsByYear W20346330702022 @default.
- W2034633070 crossrefType "journal-article" @default.
- W2034633070 hasAuthorship W2034633070A5052577601 @default.
- W2034633070 hasAuthorship W2034633070A5078371702 @default.
- W2034633070 hasConcept C121332964 @default.
- W2034633070 hasConcept C148898269 @default.
- W2034633070 hasConcept C155647269 @default.
- W2034633070 hasConcept C161790260 @default.
- W2034633070 hasConcept C178790620 @default.
- W2034633070 hasConcept C179104552 @default.
- W2034633070 hasConcept C185592680 @default.
- W2034633070 hasConcept C2776673659 @default.
- W2034633070 hasConcept C2778142098 @default.
- W2034633070 hasConcept C2779692420 @default.
- W2034633070 hasConcept C37329643 @default.
- W2034633070 hasConcept C54175244 @default.
- W2034633070 hasConcept C62520636 @default.
- W2034633070 hasConcept C75473681 @default.
- W2034633070 hasConceptScore W2034633070C121332964 @default.
- W2034633070 hasConceptScore W2034633070C148898269 @default.
- W2034633070 hasConceptScore W2034633070C155647269 @default.
- W2034633070 hasConceptScore W2034633070C161790260 @default.
- W2034633070 hasConceptScore W2034633070C178790620 @default.
- W2034633070 hasConceptScore W2034633070C179104552 @default.
- W2034633070 hasConceptScore W2034633070C185592680 @default.
- W2034633070 hasConceptScore W2034633070C2776673659 @default.
- W2034633070 hasConceptScore W2034633070C2778142098 @default.
- W2034633070 hasConceptScore W2034633070C2779692420 @default.
- W2034633070 hasConceptScore W2034633070C37329643 @default.
- W2034633070 hasConceptScore W2034633070C54175244 @default.
- W2034633070 hasConceptScore W2034633070C62520636 @default.
- W2034633070 hasConceptScore W2034633070C75473681 @default.
- W2034633070 hasIssue "3" @default.
- W2034633070 hasLocation W20346330701 @default.
- W2034633070 hasOpenAccess W2034633070 @default.
- W2034633070 hasPrimaryLocation W20346330701 @default.
- W2034633070 hasRelatedWork W1963487763 @default.
- W2034633070 hasRelatedWork W1967960162 @default.
- W2034633070 hasRelatedWork W1986223035 @default.
- W2034633070 hasRelatedWork W2034277154 @default.
- W2034633070 hasRelatedWork W2034633070 @default.
- W2034633070 hasRelatedWork W2328302006 @default.
- W2034633070 hasRelatedWork W2350327680 @default.
- W2034633070 hasRelatedWork W2393057017 @default.
- W2034633070 hasRelatedWork W33117927 @default.
- W2034633070 hasRelatedWork W350956248 @default.
- W2034633070 hasVolume "25" @default.
- W2034633070 isParatext "false" @default.
- W2034633070 isRetracted "false" @default.
- W2034633070 magId "2034633070" @default.
- W2034633070 workType "article" @default.