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- W2034641118 abstract "The keto–enol equilibrium of 2-acetylcyclopentanone (ACPE) was studied in water by analysing the effect that aqueous micellar solutions produce in the UV absorption spectrum of this compound. Aqueous solutions of anionic, cationic, or nonionic surfactants forming micelles have been used. The quantitative treatment of absorbance changes measured at the maximum absorption wavelength as a function of surfactant concentration gave the keto–enol equilibrium constant, KE. In the same sense, the analysis of spectral changes measured as a function of pH in aqueous basic media allowed us to determine the acidity equilibrium constant, Ka. The combination of both equilibrium constants gives the acidity constant of the enol ionizing as an oxygen acid, pKEa = 7.72 and the acidity constant of the ketone ionizing as a carbon acid, pKKa = 8.12. The kinetic study of the nitrosation reaction of ACPE has been realized in aqueous strong acid media under several experimental conditions. As expected, the reaction is first-order with respect to ACPE concentration, but in sharp contrast to other β-dicarbonyl compounds, the dependence of both [H+] or [X−] (X− = Cl−, Br−, or SCN−) is not simple first-order; instead a fractional order which varied from 1 to 0 was observed. The kinetic interpretation of these experimental facts has been done on the basis of a reaction mechanism that considers the formation of an intermediate in steady-state, which has been postulated as a chelate-nitrosyl complex. The quantitative treatment of the experimental data gave the values of every rate constant appearing in the proposed reaction mechanism." @default.
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- W2034641118 date "2002-01-01" @default.
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- W2034641118 title "Keto–enol/enolate equilibria in the 2-acetylcyclopentanone system. An unusual reaction mechanism in enol nitrosation" @default.
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- W2034641118 doi "https://doi.org/10.1039/b202981m" @default.
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