FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034642810> ?p ?o ?g. }

• W2034642810 endingPage "3866" @default.
• W2034642810 startingPage "3856" @default.
• W2034642810 abstract "Reduction of the tetravalent complex [{2,5-[(C4H3N)CPh2]2[C4H2N(Me)]}ThCl2 (THF)]·THF (2) of the tripyrrolide dianion 2,5-[(C4H3N)CPh2]2C4H2N(Me) afforded different products depending on the reaction conditions. In every case, the reaction proceeded via the initial formation of a reduced species, as indicated by the very rapid formation of a dark red color followed by slow and complete discoloration. In the case of the reduction in toluene, the complexes ({2,5-[(C4H3N)CPh2]2[C4H2N]}2Th[K(toluene)]2)·1.5(toluene) (3a) and {2,5-[(C4H3N)CPh2]2[C4H2N]}2Th[K(DME)]2 (3b) were obtained, depending on the crystallization solvent (toluene versus DME). In both cases, the products arose from a loss of the methyl group attached to the central pyrrole ring N atom. When the reduction was carried out in DME as a solvent, the complex {[{2,5-[(C4H3N)CPh2]2[C4H2N(Me)]}Th(OMe)]2(m-OC2H4OMe)2}· 0.75(hexane) (5) was isolated. This species is derived from two different pathways of C−O cleavage of the DME solvent. Reduction of {2,5-[(C4H3N)CPh2]2[C4H2N(Me)]}ThCl{(C4H3N)CPh2[C4H3N(Me)]} (6), containing both the monoalkylated tripyrrolide and dipyrrolide ligands, afforded instead pyrrolide ring opening and formation of [({2,5-[(C4H3N)CPh2]2[C4H2N(Me)]}Th[(C4H3N)CPh2(CCHCHCHNMe)])2(m-K)][K(DME)4]·2(hexane) (7)." @default.
• W2034642810 created "2016-06-24" @default.
• W2034642810 creator A5026611636 @default.
• W2034642810 creator A5063225492 @default.
• W2034642810 creator A5069548343 @default.
• W2034642810 creator A5089743655 @default.
• W2034642810 date "2006-07-01" @default.
• W2034642810 modified "2023-10-02" @default.
• W2034642810 title "Ring Opening and C−O and C−N Bond Cleavage by Transient Reduced Thorium Species" @default.
• W2034642810 cites W1968399337 @default.
• W2034642810 cites W1975468004 @default.
• W2034642810 cites W1975964562 @default.
• W2034642810 cites W1976921598 @default.
• W2034642810 cites W1981180548 @default.
• W2034642810 cites W1982749629 @default.
• W2034642810 cites W1982861161 @default.
• W2034642810 cites W1992129888 @default.
• W2034642810 cites W1997408457 @default.
• W2034642810 cites W1998950262 @default.
• W2034642810 cites W2004853738 @default.
• W2034642810 cites W2006879276 @default.
• W2034642810 cites W2014743618 @default.
• W2034642810 cites W2021571036 @default.
• W2034642810 cites W2021598539 @default.
• W2034642810 cites W2024120411 @default.
• W2034642810 cites W2038431710 @default.
• W2034642810 cites W2039902128 @default.
• W2034642810 cites W2042777752 @default.
• W2034642810 cites W2042903457 @default.
• W2034642810 cites W2049799267 @default.
• W2034642810 cites W2055038447 @default.
• W2034642810 cites W2076920173 @default.
• W2034642810 cites W2088632303 @default.
• W2034642810 cites W2091000379 @default.
• W2034642810 cites W2094056928 @default.
• W2034642810 cites W2122764772 @default.
• W2034642810 cites W2140300887 @default.
• W2034642810 cites W2144332006 @default.
• W2034642810 cites W2145637808 @default.
• W2034642810 cites W2158573995 @default.
• W2034642810 cites W2413091549 @default.
• W2034642810 cites W2949533998 @default.
• W2034642810 doi "https://doi.org/10.1021/om060454q" @default.
• W2034642810 hasPublicationYear "2006" @default.
• W2034642810 type Work @default.
• W2034642810 sameAs 2034642810 @default.
• W2034642810 citedByCount "60" @default.
• W2034642810 countsByYear W20346428102012 @default.
• W2034642810 countsByYear W20346428102013 @default.
• W2034642810 countsByYear W20346428102014 @default.
• W2034642810 countsByYear W20346428102015 @default.
• W2034642810 countsByYear W20346428102016 @default.
• W2034642810 countsByYear W20346428102017 @default.
• W2034642810 countsByYear W20346428102018 @default.
• W2034642810 countsByYear W20346428102019 @default.
• W2034642810 countsByYear W20346428102020 @default.
• W2034642810 countsByYear W20346428102021 @default.
• W2034642810 countsByYear W20346428102022 @default.
• W2034642810 countsByYear W20346428102023 @default.
• W2034642810 crossrefType "journal-article" @default.
• W2034642810 hasAuthorship W2034642810A5026611636 @default.
• W2034642810 hasAuthorship W2034642810A5063225492 @default.
• W2034642810 hasAuthorship W2034642810A5069548343 @default.
• W2034642810 hasAuthorship W2034642810A5089743655 @default.
• W2034642810 hasConcept C155647269 @default.
• W2034642810 hasConcept C161790260 @default.
• W2034642810 hasConcept C178790620 @default.
• W2034642810 hasConcept C185592680 @default.
• W2034642810 hasConcept C2777077568 @default.
• W2034642810 hasConcept C2778142098 @default.
• W2034642810 hasConcept C2780378348 @default.
• W2034642810 hasConcept C2780471494 @default.
• W2034642810 hasConcept C3044715 @default.
• W2034642810 hasConcept C71240020 @default.
• W2034642810 hasConceptScore W2034642810C155647269 @default.
• W2034642810 hasConceptScore W2034642810C161790260 @default.
• W2034642810 hasConceptScore W2034642810C178790620 @default.
• W2034642810 hasConceptScore W2034642810C185592680 @default.
• W2034642810 hasConceptScore W2034642810C2777077568 @default.
• W2034642810 hasConceptScore W2034642810C2778142098 @default.
• W2034642810 hasConceptScore W2034642810C2780378348 @default.
• W2034642810 hasConceptScore W2034642810C2780471494 @default.
• W2034642810 hasConceptScore W2034642810C3044715 @default.
• W2034642810 hasConceptScore W2034642810C71240020 @default.
• W2034642810 hasIssue "16" @default.
• W2034642810 hasLocation W20346428101 @default.
• W2034642810 hasOpenAccess W2034642810 @default.
• W2034642810 hasPrimaryLocation W20346428101 @default.
• W2034642810 hasRelatedWork W2006329413 @default.
• W2034642810 hasRelatedWork W2023068353 @default.
• W2034642810 hasRelatedWork W2027054448 @default.
• W2034642810 hasRelatedWork W2054623568 @default.
• W2034642810 hasRelatedWork W2065018313 @default.
• W2034642810 hasRelatedWork W2224560979 @default.
• W2034642810 hasRelatedWork W2283821597 @default.
• W2034642810 hasRelatedWork W2942999599 @default.
• W2034642810 hasRelatedWork W2979073295 @default.
• W2034642810 hasRelatedWork W3015847618 @default.

• next