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- W2034643532 abstract "We prepared a homologous series of S-shaped oligomers, 4,4′-bis(ω-(2-(ω-(4-(cyanophenyl)phenyloxy)alkyloxy)phenyloxy)alkyloxy)biphenyl [ I-(m,n) ], and investigated effects of the spacer length on the phase transition behavior. I-(7,7), I-(8,8), I-(9,9) and I-(7,9) showed nematic (N) and smectic A (SmA) phases, whereas I-(6,6) and I-(6,9) showed only an N phase. The melting behavior was found to depend on the parity of the spacer ( m ). The liquid-crystalline phases of I-(8,8) and I-(6,9) are monotropic, however, those of I-(9,9) and I-(7,9) are enantiotropic. X-ray diffraction measurements of I-(7,7), I-(8,8) and I-(7,9) indicate that the S-shaped oligomers exist as a close-packed structure in the monolayer SmA phase." @default.
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- W2034643532 date "2009-09-03" @default.
- W2034643532 modified "2023-09-23" @default.
- W2034643532 title "Molecular Organization of Preorganized S-Shaped Oligomers in the Liquid Crystalline Phases" @default.
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- W2034643532 doi "https://doi.org/10.1080/15421400903054527" @default.
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