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• W2034647729 startingPage "4063" @default.
• W2034647729 abstract "Isothermal field-assisted sintering of two-phase, 50 vol% 3YSZ-alumina composites exhibit an incubation time for the onset of the flash event. Weaker applied fields and lower temperatures lengthen the incubation period. The effect is highly non-linear. For example at 1300 °C and 150 V cm−1 the flash occurs nearly instantaneously (in 10 s), but extends to 2 h at 1275 °C and 65 V cm−1. This behavior is reminiscent of nucleation and growth phenomena in chemically driven experiments involving phase transformations in the solid state. Here, a model for nucleation under electrical driving forces, based upon the growth of embryos of colossal permittivity is presented. Nucleation is the precursor to the onset of a flash. Therefore it occurs at the furnace temperature. Joule heating is a consequence of nucleation not the cause of it." @default.
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• W2034647729 date "2014-12-01" @default.
• W2034647729 modified "2023-10-16" @default.
• W2034647729 title "Flash sintering as a nucleation phenomenon and a model thereof" @default.
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• W2034647729 doi "https://doi.org/10.1016/j.jeurceramsoc.2014.04.043" @default.
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