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- W2034648655 abstract "Abstract The kinetics of the gas phase reaction between OH and ClNO 2 have been studied in a fast flow discharge system (FFDS) at 298 K. The rate constant for the reaction was determined in phosphoric acid or halocarbon was coated flow tubes to be (3.5 ± 0.7) × 10 −14 cm 3 molecule −1 s −1 , where the uncertainty takes into account possible systematic errors and is greater than 2σ. HOCl was shown by mass spectrometry to be the major product. Using for comparison the OH + ClNO reaction, these data show that channel (1a) OH + ClNO 2 → HOCl + NO 2 must account for ⩾ 90% of the OH + ClNO 2 reaction. A second possible channel (1b) OH + ClNO 2 → HNO 3 + Cl is not significant. The atmospheric implication of these results are discussed." @default.
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- W2034648655 date "1991-04-01" @default.
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- W2034648655 title "The reaction of OH with ClNO2 at 298 K: kinetics and mechanisms" @default.
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- W2034648655 doi "https://doi.org/10.1016/0009-2614(91)90317-3" @default.
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