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• W2034650725 abstract "In this article, we report unique reactivities of hydrogensulfide (SH), disulfide (S2), and oxydisulfide ligands (S2On: n = 1-4) bridging between the Rh—Rh/Ir—Ir bonds. The hydrogensulfide and the disulfide ligand give rise to the S—C and C—C bond formation and the multi C—Cl bond activation, respectively. The oxydisulfide ligand (S2O4) shows a photoisomerization resulting in an intriguing crystalline-state photochromism. These reactivities are attributed mainly to the electron-rich Rh—Rh/Ir—Ir bond and the geometrical arrangement and the electronic character of the sulfide ligands." @default.
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• W2034650725 date "2007-01-01" @default.
• W2034650725 modified "2023-10-16" @default.
• W2034650725 title "Transformation of Inorganic Sulfurs Using Rhodium/Iridium Dinuclear Complexes" @default.
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• W2034650725 doi "https://doi.org/10.4019/bjscc.50.2" @default.
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