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- W2034652541 abstract "Abstract In this study the surface oxidation of a number of nickel-rich NiZr alloys is reported as a means to determine its role on the stability of amorphous zirconium-based metallic glasses. The evolution of the oxide layer was monitored by following the nickel and zirconium XPS peaks after exposure to an oxygen pressure of 10 −5 mbar for various periods. The surface of the air-exposed films is characterized as ZrO 2 even for bulk nickel concentrations over 80 at.%. After sputter cleaning, oxidation at room temperature under controlled oxygen exposure results in a several-stage oxidation towards ZrO 2 accompanied by a systematic depletion of the nickel at the surface. This reaction saturates after exposures of the order of several thousand Langmuirs. Throughout this process, nickel remains primarily in a metallic state. There is, moreover, indirect transport evidence that a non-surface nickel-rich layer is produced." @default.
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- W2034652541 date "1991-03-01" @default.
- W2034652541 modified "2023-09-28" @default.
- W2034652541 title "Oxidation of amorphous NiZr sputtered films" @default.
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- W2034652541 doi "https://doi.org/10.1016/0921-5093(91)90915-a" @default.
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