FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034659188> ?p ?o ?g. }

• W2034659188 endingPage "113" @default.
• W2034659188 startingPage "105" @default.
• W2034659188 abstract "Photophysical and photochemical properties for 4,6-diphenyl-3-cyanopyridin-2(1H) thione (CPPT) and 4-phenyl-6-toly-3-cyanopyridin-2(1H)-thione (CMPT) have been investigated by various spectroscopic methods including transient absorption. With changing the solvent polarity, CPPT and CMPT exhibited the thione-thiol tautomeric equilibria. Laser flash photolysis studies in polar solvents and protic solvents have revealed that triplet state formation was predominantly observed by the thione tautomer, which was supported by the characteristic self-quenching in the rate constants of (2.99–5.68)×109 dm3 mol−1. In nonopolar and less polar solvents, on the other hand, the thio radical was observed by photoinduced homolytic SH bond cleavage of the thiol form. Absorption and fluorescence spectra indicate the considerable shifts with the solvent polarity in each form in addition to the equilibria. From the fluorescence lifetimes, the tautomeric forms can also be discriminated." @default.
• W2034659188 created "2016-06-24" @default.
• W2034659188 creator A5040618201 @default.
• W2034659188 creator A5057413296 @default.
• W2034659188 creator A5080787029 @default.
• W2034659188 date "2000-12-01" @default.
• W2034659188 modified "2023-09-28" @default.
• W2034659188 title "Photophysical characteristics of two 4,6-disubistituted-3-cyanopyridin-2(1H)-thiones in various solvents" @default.
• W2034659188 cites W1964265758 @default.
• W2034659188 cites W1966946742 @default.
• W2034659188 cites W1969526079 @default.
• W2034659188 cites W1971308611 @default.
• W2034659188 cites W1979118506 @default.
• W2034659188 cites W1980580741 @default.
• W2034659188 cites W1990543635 @default.
• W2034659188 cites W1991527977 @default.
• W2034659188 cites W1996877293 @default.
• W2034659188 cites W1998294641 @default.
• W2034659188 cites W2009111954 @default.
• W2034659188 cites W2013600629 @default.
• W2034659188 cites W2015436959 @default.
• W2034659188 cites W2030299964 @default.
• W2034659188 cites W2034225086 @default.
• W2034659188 cites W2047448894 @default.
• W2034659188 cites W2047744816 @default.
• W2034659188 cites W2048934611 @default.
• W2034659188 cites W2055207062 @default.
• W2034659188 cites W2066059176 @default.
• W2034659188 cites W2069452265 @default.
• W2034659188 cites W2074521835 @default.
• W2034659188 cites W2077538161 @default.
• W2034659188 cites W2084628110 @default.
• W2034659188 cites W2087229170 @default.
• W2034659188 cites W2092894799 @default.
• W2034659188 cites W2145434936 @default.
• W2034659188 cites W2159162083 @default.
• W2034659188 cites W2163323107 @default.
• W2034659188 cites W2332299550 @default.
• W2034659188 cites W2338778863 @default.
• W2034659188 cites W2477211618 @default.
• W2034659188 cites W2949302322 @default.
• W2034659188 cites W2953338007 @default.
• W2034659188 doi "https://doi.org/10.1016/s1010-6030(00)00359-2" @default.
• W2034659188 hasPublicationYear "2000" @default.
• W2034659188 type Work @default.
• W2034659188 sameAs 2034659188 @default.
• W2034659188 citedByCount "4" @default.
• W2034659188 crossrefType "journal-article" @default.
• W2034659188 hasAuthorship W2034659188A5040618201 @default.
• W2034659188 hasAuthorship W2034659188A5057413296 @default.
• W2034659188 hasAuthorship W2034659188A5080787029 @default.
• W2034659188 hasConcept C111233374 @default.
• W2034659188 hasConcept C121332964 @default.
• W2034659188 hasConcept C121745418 @default.
• W2034659188 hasConcept C125287762 @default.
• W2034659188 hasConcept C132439834 @default.
• W2034659188 hasConcept C13472781 @default.
• W2034659188 hasConcept C139066938 @default.
• W2034659188 hasConcept C148898269 @default.
• W2034659188 hasConcept C175689099 @default.
• W2034659188 hasConcept C178790620 @default.
• W2034659188 hasConcept C185592680 @default.
• W2034659188 hasConcept C24890656 @default.
• W2034659188 hasConcept C2779607525 @default.
• W2034659188 hasConcept C2780471494 @default.
• W2034659188 hasConcept C2781324293 @default.
• W2034659188 hasConcept C32891209 @default.
• W2034659188 hasConcept C62520636 @default.
• W2034659188 hasConcept C75473681 @default.
• W2034659188 hasConcept C91881484 @default.
• W2034659188 hasConcept C93391505 @default.
• W2034659188 hasConcept C95503338 @default.
• W2034659188 hasConceptScore W2034659188C111233374 @default.
• W2034659188 hasConceptScore W2034659188C121332964 @default.
• W2034659188 hasConceptScore W2034659188C121745418 @default.
• W2034659188 hasConceptScore W2034659188C125287762 @default.
• W2034659188 hasConceptScore W2034659188C132439834 @default.
• W2034659188 hasConceptScore W2034659188C13472781 @default.
• W2034659188 hasConceptScore W2034659188C139066938 @default.
• W2034659188 hasConceptScore W2034659188C148898269 @default.
• W2034659188 hasConceptScore W2034659188C175689099 @default.
• W2034659188 hasConceptScore W2034659188C178790620 @default.
• W2034659188 hasConceptScore W2034659188C185592680 @default.
• W2034659188 hasConceptScore W2034659188C24890656 @default.
• W2034659188 hasConceptScore W2034659188C2779607525 @default.
• W2034659188 hasConceptScore W2034659188C2780471494 @default.
• W2034659188 hasConceptScore W2034659188C2781324293 @default.
• W2034659188 hasConceptScore W2034659188C32891209 @default.
• W2034659188 hasConceptScore W2034659188C62520636 @default.
• W2034659188 hasConceptScore W2034659188C75473681 @default.
• W2034659188 hasConceptScore W2034659188C91881484 @default.
• W2034659188 hasConceptScore W2034659188C93391505 @default.
• W2034659188 hasConceptScore W2034659188C95503338 @default.
• W2034659188 hasIssue "2-3" @default.
• W2034659188 hasLocation W20346591881 @default.
• W2034659188 hasOpenAccess W2034659188 @default.
• W2034659188 hasPrimaryLocation W20346591881 @default.
• W2034659188 hasRelatedWork W1992767570 @default.

• next