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- W2034663852 abstract "Abstract This research reports on the oxidation of different amines such as dibutylamine, diethylamine, dipropylamine, ethylamine, ethylmethylamine, propylamine, triethylamine, and trimethylamine by 0.001 M potassium ferricyanide in the presence of 0.03 M NaOH at 25°C in aqueous medium and/or in 0.03 M N,N ‐dimethyldodecylamine N ‐oxide (DDAO). Oxidation rates were studied with a spectrophotometer at 420 nm. The experimental data showed that the reaction was first‐order with respect to [amine] T and [Fe(CN) 6 ] 3− . Also, the rate constant ( k obs ) had values within the concentration range of 0.015–0.05 M of NaOH and increased above the critical micelle concentration values of DDAO. The dependence of the reaction rate on the nature of the salt was also investigated, and the thermodynamic parameters Δ G * , Δ H * , and Δ S * were calculated. A pseudo‐phase model was applied to the system, and the binding constant of the amine to DDAO micelles was calculated." @default.
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- W2034663852 date "2005-01-01" @default.
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- W2034663852 title "Study of the kinetics of oxidation of amines by potassium ferricyanide in the presence of N,N-dimethyldodecylamine N-oxide" @default.
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- W2034663852 doi "https://doi.org/10.1007/s11743-005-0334-6" @default.
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