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- W2034664524 abstract "The deuterium isotope effect on the 13C NMR chemical shifts of some α-2-hydroxyaryl-N-phenylnitrones (Schiff base N-oxides) was studied. The existence of an intramolecular hydrogen bond with the proton localized on the phenolic oxygen atom was evidenced. Exceptionally large isotope effects ΔC-2(D) and ΔC-α(D) suggest that the substitution of the proton of the OH group by deuterium leads to a weakening of the hydrogen bond and some conformational changes in the molecule. This conclusion was drawn on the basis of a comparison of the deuterium isotope effects of Schiff base N-oxides and parent Schiff bases. Copyright © 2001 John Wiley & Sons, Ltd." @default.
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- W2034664524 date "2001-01-01" @default.
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- W2034664524 title "Deuterium isotope effects on13C NMR chemical shifts of some ?-(2-hydroxyaryl)-N-phenylnitrones (Schiff baseN-oxides)" @default.
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- W2034664524 doi "https://doi.org/10.1002/mrc.878" @default.
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