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• W2034665421 abstract "General conclusions concerning the nature of the B … ClF interaction follow from the behaviour of the properties of sixteen gas-phase complexes as the Lewis base B varies. Electric charge redistribution within ClF is small for most B … ClF considered (Mulliken outer complexes) but examples of the inner type [BCl]+ … F− having significant charge transfer are identified. Angular geometries in the series B … ClF and B … HCl are strikingly parallel. However, when the symmetry is Cs, the Z … HCl systems (Z = acceptoratom) are significantly nonlinear while the Z … Cl-F are all nearly collinear. Rules for predicting angular geometries in B … HCl are refined and extended to B … ClF." @default.
• W2034665421 created "2016-06-24" @default.
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• W2034665421 date "1997-11-01" @default.
• W2034665421 modified "2023-09-30" @default.
• W2034665421 title "Nature of complexes B … ClF in the gas phase: Conclusions from systematic variation of the Lewis base B and a comparison of the B … ClF/B … HCl series." @default.
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• W2034665421 doi "https://doi.org/10.1016/s0009-2614(97)01095-6" @default.
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