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- W2034667268 abstract "Synthesis of enantiopure 2,4-methanovalines has been achieved by means of asymmetric Strecker synthesis starting from racemic 2-methylcyclobutanone. The trans-configured α-amino acids were obtained from cyanide additions carried out in methanol, whereas the cis-configured 2,4-methanovalines were accessible via reactions in hexane. Relative stereochemistry was elucidated from NOESY experiments, while absolute configurations were assigned from X-ray crystallographic analysis." @default.
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- W2034667268 date "2003-02-01" @default.
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- W2034667268 title "Cyclobutane amino acids (CBAAs): asymmetric Strecker synthesis of enantiopure cis- and trans-2,4-methanovalines" @default.
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- W2034667268 doi "https://doi.org/10.1016/s0957-4166(02)00868-6" @default.
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