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• W2034668788 abstract "Cholesteryl oleate, selectively deuterated at various positions along the acyl chain, has been incorporated into fresh human serum low-density lipoprotein (LDL2). Temperature-dependent 2H-NMR spectra were recorded between 15 and 45°C. For deuterons at C-2' and C-5' of the acyl chain, two 2-NMR spectral components, a broad and a narrow signal, are observed. This is interpreted as reflecting the coexistence of two cholesteryl ester regions in the LDL2 core which possess different degrees of order. The C-2 bond order parameters, SCD, are approx. 0.12–0.20 for the more ordered region and approx. 0.04–0.06 for the less ordered region. Longitudinal relaxation times, T1 of deuterated cholesteryl oleate are found to increase between C-8' and the terminal -C2H3 group, which is consistent with an increased rate of chain motion toward the free ends of the ester acyl chains." @default.
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• W2034668788 date "1986-06-01" @default.
• W2034668788 modified "2023-09-27" @default.
• W2034668788 title "Orientational order of cholesteryl oleate in low-density lipoprotein observed by 2H-NMR" @default.
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• W2034668788 doi "https://doi.org/10.1016/0005-2760(86)90135-9" @default.
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• W2034668788 hasPublicationYear "1986" @default.
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