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- W2034669953 abstract "Abstract The adsorption and desorption behaviors of Pb2+ on D113-III resin were investigated with various chemical methods. The influence of operational conditions such as contact time, initial concentration, initial pH of solution, and temperature on the adsorption of Pb2+ has also been examined. The results show that the maximum uptake capacity of Pb2+ is 476.2 mg/g on D113-III resin at 298 K at pH = 4.5 in HAc–NaAc medium. The adsorption of Pb2+ fitted the Langmuir isotherm better than the Freundlich isotherm. And kinetics on the adsorption of Pb2+ has been studied. The apparent activation energy E a and adsorption rate constant k 298 values are 5.22 kJ/mol and 5.82 × 10−5 s−1, respectively. The data of thermodynamic parameters whose ΔS value is 0.255 kJ/mol K and ΔH value is 45.29 kJ/mol indicate the endothermic nature of the adsorption process. And the negative value of ΔG showed that the adsorption of Pb2+ ions onto D113-III resin was spontaneous. The Thomas model was applied to experimental data obtained from column adsorption experiments. Finally, Pb2+ can be eluted by using 0.5 mol/L HCl solution and the resin can be regenerated and reused. And the sorption of Pb2+ on D113-III resin from simulated seawater is studied. Keywords: D113-III resinPb2+ AdsorptionSorption kineticsThermodynamic Acknowledgments This research was funded by the grants from the National Key Technology Research and Development Program of China (No. 2008BAD94B09) and the Special Major Science and Technology Project of Zhejiang Province, China (Project. 2011C11098). It was also supported by Key Laboratory of Advanced Textile Materials and Manufacturing Technology (Zhejiang Sci-tech University), Ministry of Education, 2011007." @default.
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- W2034669953 date "2012-03-01" @default.
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- W2034669953 title "Study on the adsorption of Pb<sup>2+</sup>from aqueous solution by D113-III resin" @default.
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- W2034669953 doi "https://doi.org/10.1080/19443994.2012.664679" @default.
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