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- W2034671631 abstract "A detailed understanding of the reaction mechanisms would be useful to predict and control the ability of fixation systems to retard the solu- bility and/or mobility of the incorporated metal species. For the present study, the interactions between tricalcium aluminate (C3A) paste and CuO were characterized using transmission electron microscopy (TEM) equipped with energy-dispersive X-ray analysis (EDAX). The results of TEM/EDAX analyses indicated that the concentration gradient of copper species in the hydrated C3A region and physical entrapment of CuO within five principal hydration products of C3A were attributed to the interactions of hydrated C3A and CuO. Additionally, no intermediate phases or new chemical products of copper related compounds existed in the five typical interfaces. No diffraction patterns of metal copper, CuO, Cu(OH)2, and CuCO3 compounds were observed in the hydrated C3A. It was thus suggested that the CuO was stabilized in the C3A paste by two major chanisms; the heterogeneous solid solution of copper species was present in the hydrated C3A and CuO was physically entrapped by the hydration products of C3A." @default.
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- W2034671631 date "1994-01-01" @default.
- W2034671631 modified "2023-09-23" @default.
- W2034671631 title "Mechanisms of metal stabilization in cementitious matrix: Transmission electron microscopic study of C3A/CuO fixation system" @default.
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- W2034671631 doi "https://doi.org/10.1016/0304-3894(93)e0052-4" @default.
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