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- W2034672065 abstract "Transient heteronuclear Overhauser effects were observed between 133Cs and 1H by two-dimensional heteronuclear Overhauser effect spectroscopy (HOESY). In caesium tetraphenylborate (CsBPh4) dissolved in pyridine-d5, Cs+ is tightly attached to the BPh4− anion, thus forming a contact ion pair (CIP). By contrast, after addition of one equivalent of the crown ether 18-crown-6, caesium is located intimately at the site of the crown ether whereas the tetraphenylborate anion is remote (solvent-separated ion pair, SSIP). The results are in agreement with experiments described earlier by Mei et al. Similar observations were made for caesium 3-methylpentyl 3-oxide in tetrahydrofuran-d8 solution. 133Cs, 1H HOESY indicates the presence of a contact ion pair. Steady-state 133Cs {1H} experiments on the latter compound reveal weak fractional enhancements of 0.2%." @default.
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- W2034672065 date "1991-05-01" @default.
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- W2034672065 title "133Cs,1H two-dimensional heteronuclear Overhauser effect spectroscopy (HOESY): Structural analysis of organic caesium compounds by detection of short Cs,H contacts" @default.
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- W2034672065 doi "https://doi.org/10.1002/mrc.1260290514" @default.
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