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• W2034674568 abstract "We investigated AlnS− (n=3–15) and AlnS2− (n=7–15) clusters with mass spectrometry and photoelectron spectroscopy. We found that Al13 is relatively robust when it reacts with sulfur atoms, indicating that it has some superatomic character. However, Al13 cannot be simply considered as a superatom when it interacts with sulfur due to the following reasons: Al13’s icosahedral structure has been distorted slightly by sulfur atoms; the vertical detachment energies and adiabatic detachment energies of Al13S− and Al13S2− clusters are not significantly different from those of their neighboring clusters; and the charge distributions in Al13S− and Al13S2− do not necessarily associate with superatomic behavior of Al13." @default.
• W2034674568 created "2016-06-24" @default.
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• W2034674568 date "2010-04-26" @default.
• W2034674568 modified "2023-10-04" @default.
• W2034674568 title "Communications: Investigation of the superatomic character of Al13 via its interaction with sulfur atoms" @default.
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• W2034674568 doi "https://doi.org/10.1063/1.3374431" @default.
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