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• W2034676841 endingPage "2172" @default.
• W2034676841 startingPage "2165" @default.
• W2034676841 abstract "Iso-cetane (2,2,4,4,6,8,8-heptamethylnonane, C{sub 16}H{sub 34}) is a highly branched alkane reference compound for determining cetane ratings. It is also a candidate branched alkane representative in surrogate mixtures for diesel and jet fuels. Here new experiments and kinetic modeling results are presented for the autoignition of iso-cetane at elevated temperatures and pressures relevant to combustion in internal combustion engines. Ignition delay time measurements were made in reflected shock experiments in a heated shock tube for {phi} = 0.5, 1.0, and 1.5 iso-cetane/air mixtures at temperatures ranging from 879 to 1347 K and pressures from 8 to 47 atm. Ignition delay times were measured using electronically excited OH emission, monitored through the shock tube end wall, and piezoelectric pressure transducer measurements, made at side wall locations. A new kinetic mechanism for the description of the oxidation of iso-cetane is presented that is developed based on a previous mechanism for iso-octane. Computed results from the mechanism are found in good agreement with the experimental measurements. To our knowledge, the ignition time measurements for iso-cetane presented here are the first of their kind. (author)" @default.
• W2034676841 created "2016-06-24" @default.
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• W2034676841 date "2009-11-01" @default.
• W2034676841 modified "2023-10-01" @default.
• W2034676841 title "The autoignition of iso-cetane at high to moderate temperatures and elevated pressures: Shock tube experiments and kinetic modeling" @default.
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• W2034676841 doi "https://doi.org/10.1016/j.combustflame.2009.05.007" @default.
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